The structure control, especially at the nanoscale, is of the utmost importance in the field of the materials science of thin films. Here, the hyperthermal ion induced self-organization caused by phase separation during the carbon-transition metal (Ni, Cu) thin film growth is reported. The films have been grown by ionized physical vapour deposition using filtered cathodic vacuum arc. Influence of the metal type, film composition, ion energy and incidence angle is studied. The film morphology has been determined by transmission electron microscopy and grazing incidence small angle x-ray scattering. At these growth conditions, atomic displacements are caused solely by impacting energetic ions, resulting in phase separation in an advancing surface layer. If the metal amount surpasses some critical value, this layer switches to an oscillatory mode and a nanoscale precipitation pattern emerges. We demonstrate that the ion induced atomic mobility is not random, as it would be in the case of thermal diffusion, but conserves to a large extent the initial direction of the incoming ions, resulting in a tilting of the periodic precipitation structures for the oblique ion incidences. The metal nanopatterns no longer align with the advancing surface, but with the incoming ions. We establish a dependence of the nanopattern morphology on the growth parameters and demonstrate a method for controlling the nanopatterning. Application of this concept opens new ways for the bottom-up nanostructure control for composite materials.

 

 

Gintautas Abrasonis, Forschungszentrum Dresden-Rossendorf, POB 51 01 19, 01314 Dresden, Germany and University of Sydney, New South Wales 2006, Australia, Germany
Thomas W. H. Oates, University of Sydney, New South Wales 2006, Australia and Linköpings University, 58183 Linköping, Sweden, Australia
György J. Kovács, Forschungszentrum Dresden-Rossendorf, POB 51 01 19, 01314 Dresden, Germany, Germany
Mark Tucker, University of Sydney, New South Wales 2006, Australia, Australia
Jörg Grenzer, Forschungszentrum Dresden-Rossendorf, POB 51 01 19, 01314 Dresden, Germany, Germany
Per O. A. Persson, Linköpings University, 58183 Linköping, Sweden, Sweden
Karl-Heinz H. Heinig, Forschungszentrum Dresden-Rossendorf, POB 51 01 19, 01314 Dresden, Germany, 
Andrius Martinavičius, Forschungszentrum Dresden-Rossendorf, POB 51 01 19, 01314 Dresden, Germany, 
Nicole Jeutter, Forschungszentrum Dresden-Rossendorf, POB 51 01 19, 01314 Dresden, Germany, 
Carsten Baehtz, Forschungszentrum Dresden-Rossendorf, POB 51 01 19, 01314 Dresden, Germany, 
Marcela M. M. Bilek, University of Sydney, New South Wales 2006, Australia, 
Wolfhard Möller*, Forschungszentrum Dresden-Rossendorf, POB 51 01 19, 01314 Dresden, Germany, 

*presenting author